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ISOPROPYLMAGNESIUM CHLORIDE - LITHIUM CHLORIDE COMPLEX

Basic information

  • Product Name:ISOPROPYLMAGNESIUM CHLORIDE - LITHIUM CHLORIDE COMPLEX
  • CasNo.:745038-86-2
  • MF:C3H7 Cl2 Mg . Li
  • MW:145.24

Physical and Chemical Properties

  • Purity:99%
  • Boiling Point:
  • Packing:
  • Throughput:
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Product Details

CasNo: 745038-86-2

MF: C3H7 Cl2 Mg . Li

Buy Quality High Grade Top Purity 99% Pure 745038-86-2 with Competitive Price

  • Molecular Formula:C3H7 Cl2 Mg . Li
  • Molecular Weight:145.24
  • Flash Point:-17 °C 
  • PSA:0.00000 
  • Density:1.05  
  • LogP:-0.94250 

Isopropylmagnesium chloride lithium chloride complex (Cas 2622-05-1) Usage

Description

Isopropylmagnesium chloride lithium chloride complex, often referred to as i-PrMgCl•LiCl, is derived from isopropylmagnesium chloride (i-PrMgCl) and lithium chloride (LiCl).

Uses

Isopropylmagnesium chloride lithium chloride complex is commonly used in organic chemistry as a source of nucleophilic alkyl groups.

745038-86-2 Relevant articles

Some t-butylmagnesium and related complexes. Reactions between hydrides and organomagnesium compounds

G. E. Coates  and  J. A. Heslop

, Journal of the Chemical Society A: Inorganic, Physical, Theoretical

Solutions of di-t-butylmagnesium have been prepared by the dioxan precipitation method, and from them several dibutylmagnesium complexes have been obtained. These include But2Mg–dioxan, which is insoluble in toluene and soluble in ether, the bistetrahydrofuran complex which is partly dissociated in benzene, and the tetramethylethylenediamine complex.

Use of 1-chlorovinyl p-tolyl sulfoxides as alkynylmagnesium chloride sources

Koto Sekiguchi, Tsutomu Kimura

, Tetrahedron Volume 139, 12 June 2023, 133439

In our previous study, we have found that the 1,2-rearrangement, called a Fritsch–Buttenberg–Wiechell (FBW) rearrangement [11], of magnesium alkylidene carbenoids 2 generated from 2,2-disubstituted sulfoxides 1 and isopropylmagnesium chloride gives internal alkynes 3 [12].