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Benzylmagnesium chloride

Basic information

  • Product Name:Benzylmagnesium chloride
  • CasNo.:6921-34-2
  • MF:C7H7ClMg
  • MW:150.891

Physical and Chemical Properties

  • Purity:99%
  • Boiling Point:
  • Packing:clear green-brown to brown-purple solution
  • Throughput:
Inquiry

Product Details

CasNo: 6921-34-2

MF: C7H7ClMg

Appearance: clear green-brown to brown-purple solution

Export 99% Pure 6921-34-2 Benzylmagnesium chloride with Best Price and Efficient Delivery

  • Molecular Formula:C7H7ClMg
  • Molecular Weight:150.891
  • Appearance/Colour:clear green-brown to brown-purple solution 
  • Boiling Point:182 °C(Press: 16 Torr) 
  • Flash Point:-17 °C 
  • PSA:0.00000 
  • Density:1.031 g/mL at 25 °C 
  • LogP:2.69180 

Benzylmagnesium chloride(Cas 6921-34-2) Application

Chemical Properties

Light gray to dark amber-grey slurry or solution

General Description

Benzylmagnesium chloride, like other Grignard reagents, is sensitive to air and moisture. It serves as a Grignard reagent.

Application

Benzylmagnesium chloride is employed as a Grignard reagent, allowing for the addition of the benzyl group (C6H5CH2-) to organic compounds. This enables the creation of more complex molecules with altered chemical properties. It is used as an alkylating reagent in various chemical reactions.

InChI:InChI=1/C7H7.ClH.Mg/c1-7-5-3-2-4-6-7;;/h2-6H,1H2;1H;/q;;+1/p-1/rC7H7Mg.ClH/c8-6-7-4-2-1-3-5-7;/h1-5H,6H2;1H/q+1;/p-1

6921-34-2 Relevant articles

Highly variable Zr-CH2-Ph bond angles in tetrabenzylzirconium: Analysis of benzyl ligand coordination modes

Rong, Yi,Al-Harbi, Ahmed,Parkin, Gerard

, p. 8208 - 8217 (2012)

Analysis of a monoclinic modification of...

Mechanism of the reaction between benzylmagnesium chloride and carbonyl compounds. A detailed study with formaldehyde

Robert A. Benkeser and Dudley C. Snyder

, J. Org. Chem. 1982, 47, 7, 1243–1249

The reaction of benzylmagnesium chloride in THF with monomeric formaldehyde has been been studied in detail.

Abnormal Reactions of Benzylmagnesium Chloride. II. The Mechanism of the o-Tolyl Rearrangement1

JR Johnson

, Journal of the American Chemical Society, 1933

Studies of the behavior of benzylmagnesium chloride toward a variety of reactants2,3 have shown thato-tolyl derivatives appear frequently among the products of the reaction.

Regioselective 1,4-conjugate addition of grignard reagents to nitrodienes in the presence of catalytic amounts of Zn(II) salts

Dhakal, Ramesh C.,Dieter, R. Karl

supporting information, p. 1362 - 1365 (2014/04/03)

Grignard reagents undergo facile regiose...

6921-34-2 Process route

benzyl chloride
100-44-7

benzyl chloride

2-methylanthracene
613-12-7

2-methylanthracene

1,1'-(1,2-ethanediyl)bisbenzene
103-29-7

1,1'-(1,2-ethanediyl)bisbenzene

toluene
108-88-3,15644-74-3,16713-13-6

toluene

benzylmagnesium chloride
6921-34-2

benzylmagnesium chloride

Conditions
Conditions Yield
With magnesium 9,10-dimethylanthracene * 3 THF; In tetrahydrofuran; for 3h; Yield given. Yields of byproduct given;
 
benzyl chloride
100-44-7

benzyl chloride

1,1'-(1,2-ethanediyl)bisbenzene
103-29-7

1,1'-(1,2-ethanediyl)bisbenzene

benzylmagnesium chloride
6921-34-2

benzylmagnesium chloride

Conditions
Conditions Yield
With magnesium; In tetrahydrofuran; 2-methyltetrahydrofuran; at 60 ℃; under 5171.62 Torr; Solvent; Temperature; Inert atmosphere; Flow reactor;
83%

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